From the measured value of E° (SmI2+–SmI2) in THF and using free energy plots, the electron transfer between samarium diiodide and acetophenone was shown to be clearly of inner-sphere nature; on the other hand, with benzyl bromide it is closer to an outer-sphere process.
R. J. Enemærke, K. Daasbjerg and T. Skrydstrup, Chem. Commun., 1999, 343 DOI: 10.1039/A809277J
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