Ring-opening of the cyclopropylmethyl lithium compound 7 to give the α-duryl thio-substituted alkyllithium compound 8 proceeds in a stereochemically defined manner at the lithium-bearing stereocentre.
R. W. Hoffmann and R. Koberstein, Chem. Commun., 1999, 33 DOI: 10.1039/A808410F
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