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Issue 11, 1999
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The preferred conformation of α-fluoroamides

Abstract

X-Ray structures of two α-fluoroamide derivatives show the O[double bond, length half m-dash]C–C–F moiety tending towards a trans planar conformation, for which ab initio calculations suggest a deep (up to 8 kcal mol1) potential minimum.

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Article information


J. Chem. Soc., Perkin Trans. 2, 1999, 2409-2411
Article type
Paper

The preferred conformation of α-fluoroamides

J. W. Banks, A. S. Batsanov, J. A. K. Howard, D. O’Hagan, H. S. Rzepa and S. Martin-Santamaria, J. Chem. Soc., Perkin Trans. 2, 1999, 2409
DOI: 10.1039/A907452J

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