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Issue 23, 1999
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A short and efficient regioselective approach to the C-6 to C-19 segment of bifurcaranes and a formal total synthesis of β-microbiotene, microbiotol and cyclocuparanol

Abstract

Employing an epoxide rearrangement based ring contraction reaction, a short and efficient regioselective approach to the C-6 to C-19 segment of the toluquinol substituted diterpenes bifurcaranes, and its extension to a formal total synthesis of the sesquiterpenes (±)-β-microbiotene, (±)-microbiotol and (±)-cyclocuparanol are described.

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Article type: Paper
DOI: 10.1039/A908033C
J. Chem. Soc., Perkin Trans. 1, 1999, 3393-3394

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    A short and efficient regioselective approach to the C-6 to C-19 segment of bifurcaranes and a formal total synthesis of β-microbiotene, microbiotol and cyclocuparanol

    A. Srikrishna and S. Anitha Nagamani, J. Chem. Soc., Perkin Trans. 1, 1999, 3393
    DOI: 10.1039/A908033C

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