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Issue 20, 1999
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Isotypical N,N-dialkylcarbamato lanthanide complexes covering a range of 11 atomic numbers: direct experimental assessment of the lanthanide contraction in trivalent molecular compounds

Abstract

The N,N-diisopropylcarbamato complexes of lanthanides(III) from neodymium (Z = 60) to ytterbium (Z = 70) were found to be isotypical, with Ln–O distances decreasing steadily with increasing Z, the lanthanide contraction in this series of molecular complexes being provisionally assigned to an increasing bond strength with increasing atomic number of the central metal atom.

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Chem. Commun., 1999, 2053-2054
Article type
Paper

Isotypical N,N-dialkylcarbamato lanthanide complexes covering a range of 11 atomic numbers: direct experimental assessment of the lanthanide contraction in trivalent molecular compounds

U. Abram, D. Belli Dell’Amico, F. Calderazzo, C. Della Porta, A. Merigo, U. Englert and F. Marchetti, Chem. Commun., 1999, 2053
DOI: 10.1039/A904792A

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