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Issue 14, 1999
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An open-framework iron phosphate with large voids, exhibiting spin-crossover

Abstract

A novel iron phosphate, [(C4N3H16)(C4N3H15)]5+-[Fe5F4(H2PO4)(HPO4)3(PO4)3]5–·H2O, consisting of a Fe–O/F–Fe network crosslinked by PO4 groups is shown to possess unusually large elliptical voids of 24 T atoms (T = Fe, P) and to exhibit a gradual low- to high-spin transformation.

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Supplementary files


Article type: Paper
DOI: 10.1039/A903683K
Chem. Commun., 1999, 1305-1306

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    An open-framework iron phosphate with large voids, exhibiting spin-crossover

    A. Choudhury, S. Natarajan, C. N. R. Rao, A. Choudhury and C. N. R. Rao, Chem. Commun., 1999, 1305
    DOI: 10.1039/A903683K

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