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Issue 15, 1999

Evidence for the participation of a high-valent iron–oxo species in stereospecific alkane hydroxylation by a non-heme iron catalyst

Abstract

The incorporation of 18O from H218O into the product of stereospecific alkane hydroxylation by [FeII(bpmen)- (CH3CN)2](ClO4)2–H2O2 provides the first strong evidence for the participation of a high-valent iron–oxo species in the mechanism of a non-heme iron catalyst.

Supplementary files

Article information


Chem. Commun., 1999, 1375-1376
Article type
Paper

Evidence for the participation of a high-valent iron–oxo species in stereospecific alkane hydroxylation by a non-heme iron catalyst

K. Chen and L. Que Jr., Chem. Commun., 1999, 1375 DOI: 10.1039/A901678C

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