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Issue 2, 1999
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Evidence for zirconocene dications in Kaminsky type catalysts

Abstract

Low temperature NMR studies indicate that the dicationic salts [Zr(η-C5H4CMe2C6H4Me-p)2]2+[MeB(C6F5)3]2 and [Zr(η-C5H4CMe2Ph)2]2+ [MeB(C6F5)3]2 are formed when the neutral compounds [Zr(η-C5H4CMe2Ph)2Me2] and [Zr(η-C5H4CMe2C6H4Me-p)2Me2] and [Zr(η-C5H4CMe2Ph)2Me2] are treated with 2 equivalents of B(C6F5)3.

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Article information


Chem. Commun., 1999, 115-116
Article type
Paper

Evidence for zirconocene dications in Kaminsky type catalysts

M. L. H. Green and J. Saßmannshausen, Chem. Commun., 1999, 115
DOI: 10.1039/A808197B

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