Jump to main content
Jump to site search

Issue 6, 1998
Previous Article Next Article

Concave reagents. Part 27.1 Steric requirements of intraannular substituents in A,D-bridged calix[6]arenes

Abstract

A series of A,D-m-xylylene bridged calix[6]arenes 5 carrying substituents of different size in 2-position of the bridge have been investigated by dynamic NMR spectroscopy and by force field methods. Molecular mechanics calculations indicate a bean shaped conformation as the global energy minimum in which the calixarene scaffold adopts a half-pinched/half-winged arrangement.

Back to tab navigation

Article information


J. Chem. Soc., Perkin Trans. 2, 1998, 1313-1318
Article type
Paper

Concave reagents. Part 27.1 Steric requirements of intraannular substituents in A,D-bridged calix[6]arenes

U. Lüning, H. Ross and I. Thondorf, J. Chem. Soc., Perkin Trans. 2, 1998, 1313
DOI: 10.1039/A801761A

Search articles by author

Spotlight

Advertisements