AlCl3-mediated decomposition of N-phenoxybenzamide derivatives in dichloromethane mainly leads to regioselective intramolecular migration of the benzamido group from the oxygen to the ortho position of the phenyl group via electron-deficient nitrogen intermediates.
E. Miyazawa, T. Sakamoto and Y. Kikugawa, J. Chem. Soc., Perkin Trans. 2, 1998, 7 DOI: 10.1039/A706488H
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