The regioselectivity of the Baeyer–Villiger oxidation of norbornan-7-ones can be steered by the distal 2-endo-substituents present. Hydrolysis of the resulting bicyclic lactones provides a stereospecific route to functionalized cyclohexanes.
G. Mehta and N. Mohal, J. Chem. Soc., Perkin Trans. 1, 1998, 505 DOI: 10.1039/A706268K
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