Issue 6, 1998

The first example of the catalytic activity of (µ-H)Os3(µ-OCNR1R2)(CO)10 clusters in the double bond migration reactions of allylic systems functionalised with an amido group

Abstract

As exemplified by the isomerisation of N-allylacetamide in the presence of hydridocarbonyl complexes (µ-H)Os3(µ-OCNR1R2)(CO)10 (R1 = H, Alk; R2 = Alk), it has been demonstrated for the first time that they are effective catalysts for the [1,2]-double bond shift under mild conditions in allylic compounds functionalised with an amido group.

Article information

Article type
Paper

Mendeleev Commun., 1998,8, 208-210

The first example of the catalytic activity of (µ-H)Os3(µ-OCNR1R2)(CO)10 clusters in the double bond migration reactions of allylic systems functionalised with an amido group

V. A. Ershova, S. V. Tkachev, A. V. Golovin and L. Y. Al't, Mendeleev Commun., 1998, 8, 208 DOI: 10.1070/MC1998v008n06ABEH000962

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