The annelation reaction of Schiff bases by ββ'-tricarbonyl compounds has been extended to 3-ethoxyimino derivatives of 2-acyl-cyclohexane-1,3-diones. The first direct synthesis of 8-aza-D-homogonanes with a modified carbonyl group at the pharmacologically significant C(17a) position has been carried out.
O. V. Gulyakevich, I. L. Rubinova, D. B. Rubinov and A. L. Mikhal'chuk, Mendeleev Commun., 1998, 8, 183 DOI: 10.1070/MC1998v008n05ABEH000954
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