Decomposition of dimethyldioxirane in the presence of tris(bipyridine)ruthenium(II) complex (RuII) is accompanied by chemi-luminescence (CL) in the infrared spectrum region (1270 nm) due to the formation of singlet oxygen; reaction between RuIII and superoxide ion, which is formed in this process via a sequence of electron-transfer reactions, is assumed to be a CL step.
D. V. Kazakov, A. I. Voloshin, V. V. Shereshovets, V. N. Yakovlev and V. P. Kazakov, Mendeleev Commun., 1998, 8, 169 DOI: 10.1070/MC1998v008n05ABEH000936
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