The synthesis of diketones 6, 11 and 17 related to the limonoid antifeedant azadiradione is achieved in 5, 4 and 5 steps, respectively, involving a Stille type coupling reaction and a stereoselective epoxide rearrangement.
A. Fernandez-Mateos, C. Merchan Moreno, R. Rubio Gonzalez and C. Tapia Hernandez, J. Chem. Res. (S), 1998, 760 DOI: 10.1039/A807130F
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