TiO(TFA)2 or TiCl3(OTf) catalyses the efficient reaction of epoxides with acetone to give the corresponding 1,3-dioxolanes in excellent yields. The reaction of chiral styrene oxide was found to be highly stereospecific.
N. Iranpoor and B. Zeynizadeh, J. Chem. Res. (S), 1998, 466 DOI: 10.1039/A801283K
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