The cleavage of unhindered steroidal epoxides by ceric ammonium nitrate affords the trans diaxial β-nitrato alcohols but other products are obtained from more hindered epoxides.
J. R. Hanson, M. Troussier, C. Uyanik and F. Viel, J. Chem. Res. (S), 1998, 118 DOI: 10.1039/A707312G
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