Recombination of radicals in the high-pressure and high-temperature limit
Part 1 Reaction CH3 + CH3
Abstract
The reaction CH3 + CH3 –(k)→ C2H6 is used in a theoretical study of radical recombination in the gas phase. Long-range attractive forces are studied with the use of adiabatic curves that describe weak reactant interactions. Provided that the kinetic rotational energy is sufficiently large, so that the orbital momentum remains smaller than the boundary value llim, the radicals form loosely bound states CH3···CH3. Such loose states are of crucial importance in the postulated reaction mechanism. At higher pressures and temperatures (T > 200 K) the maximum asymptotical rate constant for the recombination of methyl radicals is given by the expression