The homochiral form of the complex [(‘P,N’)2Ni]2+ (‘P,N’ is a phosphino–heteroatom bidentate ligand) has been found to be more stable than its heterochiral analogue due to a ‘fitting’ of the two ‘P,N’ ligands about the Ni that is reminiscent of an ‘intramolecular embrace’.
K. L. Bray, C. P. Butts, G. C. Lloyd-Jones and M. Murray, J. Chem. Soc., Dalton Trans., 1998, 1421 DOI: 10.1039/A801170B
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