Issue 6, 1998
From the journal:

Journal of the Chemical Society, Dalton Transactions

Formation of a novel µ3-borate-capped triniobium cluster via hydrolysis of a hydridotris(pyrazol-1-yl)borate ligand

Shehla Minhas,   Alan Devlin,   David T. Richens,   Attila C. Benyei  and  Philip Lightfoot  

Abstract

The novel µ3-hydroxotrioxoborato-capped cluster [Nb3{µ3-BO3(OH)}(µ-O)3{HB(pz)3}3] 1 has been obtained following evaporation to dryness of aqueous HCl solutions of [Nb3(µ3-Cl)(µ-O)3(OH2)9]4+ and treatment with ethanolic potassium hydridotris(pyrazol-1-yl)borate, K[HB(pz)3]. The capping borate group derives from hydrolysis of a HB(pz)3– ligand in the presence of the aqua precursor. Air oxidation of 1 results in complete fragmentation, loss of the borate cap and reassembly in the form of a rectangular tetranuclear oxo-bridged product.

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Article information

DOI
https://doi.org/10.1039/A708876K
Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 953-958

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Formation of a novel µ3-borate-capped triniobium cluster via hydrolysis of a hydridotris(pyrazol-1-yl)borate ligand

S. Minhas, A. Devlin, D. T. Richens, A. C. Benyei and P. Lightfoot, J. Chem. Soc., Dalton Trans., 1998, 953 DOI: 10.1039/A708876K

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