Issue 3, 1998

Aurophilicity-impaired internal molecular motion of trinuclear gold(I) complexes

Abstract

The trinuclear (chloro)gold(I) complex of the tritertiary phosphine PhP[C6H4(PPh2)-2]2 was found to have a compact unsymmetrical structure in the crystalline state which is retained in solution owing to the fixation of the gold atoms through intermetallic contacts.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 323-324

Aurophilicity-impaired internal molecular motion of trinuclear gold(I) complexes

J. Zank, A. Schier and H. Schmidbaur, J. Chem. Soc., Dalton Trans., 1998, 323 DOI: 10.1039/A708704G

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