Issue 6, 1998

Metal-directed self-assembly of two- and three-dimensional synthetic receptors

Abstract

This article reviews recent progress in the study of the transition-metal mediated self-assembly of two- and three-dimensional synthetic receptors. Whereas macrocyclization under kinetic control is undoubtedly an unfavorable process, the self-assembly strategy offers quite efficient methods for constructing macrocycles under thermodynamic control. In particular, cis-protected Pd(II) and Pt(II) blocks are quite effective in obtaining the cyclic framework from simple molecules. Examples disclosed in this article are spontaneously assembled in quantitative yields by just mixing component molecules. This approach is successfully applied to the construction of cage compounds. The self-assembly of nanosized macrocycles and cages is also discussed.

Article information

Article type
Paper

Chem. Soc. Rev., 1998,27, 417-425

Metal-directed self-assembly of two- and three-dimensional synthetic receptors

M. Fujita, Chem. Soc. Rev., 1998, 27, 417 DOI: 10.1039/A827417Z

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements