Iron complexes of the N(CH2CH2S)33– ligand; a paramagnetic, trigonal bipyramidal Fe(II) CO complex as a chelate ligand
Abstract
The paramagnetic complex anions [Fe(NS3)Cl]– [NS3 = N(CH2CH2S)33–] and[Fe(NS3)(CO)]– have been prepared and structurally characterised; with FeCl2, [Fe(NS3)(CO)]– gives the structurally characterised, linear, paramagnetic cluster complex [Fe{Fe(NS3)(CO)-S,S′}2].