The coordination behaviour of chiral 2,2′:6′,2″-terpyridines with silver(I) is solvent dependent; in acetonitrile, mononuclear [Ag(L)(MeCN)]+ complexes are formed, whereas in less coordinating solvents such as methanol or nitromethane, solid state tetranuclear bis(double helices) [{Ag2L2}2]4+ are obtained.
G. Baum, E. C. Constable, D. Fenske, C. E. Housecroft and T. Kulke, Chem. Commun., 1998, 2659 DOI: 10.1039/A807254J
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