The enantioselective Claisen rearrangement of difluorovinyl allyl ethers was achieved, for the first time, in moderate to good enantioselectivity using a chiral boron reagent as the Lewis acid.
H. Ito, A. Sato, T. Kobayashi and T. Taguchi, Chem. Commun., 1998, 2441 DOI: 10.1039/A807157H
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