meso-η1-Metalloporphyrins: preparation of palladio- and platinioporphyrins and the crystal structure of 5-[bromo-1,2-bis(diphenylphosphino)- ethanepalladio(II)]-10,20-diphenylporphyrin
Abstract
meso-η1-Palladio- and platinioporphyrins have been isolated for the first time by means of oxidative addition of bromoporphyrins to Pd(0) and Pt(0) complexes; the X-ray crystal structure of the title complex was determined.