Issue 18, 1998

Unexpected regioselectivity in the coupling of π-coordinated tritylallene with an amido ligand in molybdenum complex

Abstract

Coupling of π-coordinated tritylallene with an amido ligand was unexpectedly found to take place at the terminal carbon in the reaction of [Cp(CO)3Mo(η2-CH2[double bond, length half m-dash]C[double bond, length half m-dash]CHCPh3)][BF4] 1, with three secondary amines (dimethylamine, piperidine, morpholine).

Article information

Article type
Paper

Chem. Commun., 1998, 2027-2028

Unexpected regioselectivity in the coupling of π-coordinated tritylallene with an amido ligand in molybdenum complex

B. Huang, Y. Lin, Y. Liu and Y. Wang, Chem. Commun., 1998, 2027 DOI: 10.1039/A805689G

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