A series of dimethyl compounds of Ti(IV) have been isolated containing both cyclopentadiene and ortho-arylphenoxide ligation; reaction with [B(C6F5)3] generates corresponding cationic methyl species which eliminate methane and form [Cp(ArO)Ti{CH2B(C6F5)2}(C6F5)] derivatives.
M. G. Thorn, J. S. Vilardo, P. E. Fanwick and I. P. Rothwell, Chem. Commun., 1998, 2427 DOI: 10.1039/A805476B
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