Manganese substituted polyoxometalates (POMs), such as Li12[MnII2ZnW(ZnW9O34)2] were effective catalysts for the oxidation of alkanes to ketones with ozone in an aqueous reaction medium; a green intermediate compound observable by UV–VIS and ESR at –78 °C was postulated to be a reactive manganese ozonide species.
R. Neumann and A. M. Khenkin, Chem. Commun., 1998, 1967 DOI: 10.1039/A804396E
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