The 2H-azaphosphirene complex 1 reacts with triorganostannyl(ethoxy)acetylenes 2a,b to yield bifunctional η1-1-phosphaallene 5a,b and 1H-phosphirene complexes 6a,b; 5a,b and 6a,b are characterized by NMR spectroscopy (13C, 31P) and complex 6b by single crystal X-ray diffraction.
R. Streubel, Chem. Commun., 1998, 1761 DOI: 10.1039/A804385J
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