Issue 16, 1998

Directed reactivity at a vanadium(II) thiolate center: synthesis and structure of a novel vanadium thiolate complex and its reaction product with azobenzene

Abstract

The vanadium(II) thiolate complex [V(tmeda)(DCTP)2] [DCTP = 2,6-dichlorothiophenolate; tmeda = N,N,N′,N′-tetramethylethylenediamine] is obtained by the reaction of 2 equiv. of LiDCTP with [VCl2(tmeda)2] and reacts with azobenzene to yield the imido-containing complex [V(tmeda)(DCTP)2(≡NPh)].

Article information

Article type
Paper

Chem. Commun., 1998, 1649-1650

Directed reactivity at a vanadium(II) thiolate center: synthesis and structure of a novel vanadium thiolate complex and its reaction product with azobenzene

J. A. Davis, C. P. Davie and D. B. Sable, Chem. Commun., 1998, 1649 DOI: 10.1039/A804231D

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