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Issue 15, 1998
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Dynamic cis/trans isomerisation in a porphyrin–fullerene conjugate

Abstract

A porphyrin with two fullerene substituents is prepared by condensation of a C60 aldehyde derivative and dipyrrol-2-yl methane and by reaction of a preconstructed porphyrin with C60 itself; it is obtained as a mixture of two conformers in slow equilibrium, as shown by a variable temperature NMR study.

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Article information


Chem. Commun., 1998, 1545-1546
Article type
Paper

Dynamic cis/trans isomerisation in a porphyrin–fullerene conjugate

J. Nierengarten and J. Nicoud, Chem. Commun., 1998, 1545
DOI: 10.1039/A803434F

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