Issue 16, 1998
From the journal:

Chemical Communications

Synthesis and characterization of the monomeric molybdenum trithiolate Mo(η7-dmpt)(η1-dmpt)2 (dmpt = 2,6-dimesitylphenylthiolate)

Birsen S. Buyuktas  and  Philip P. Power  

Abstract

Treatment of MoCl3(THF)3 with 3 equiv. of LiSC6H3Mes2-2,6 (Mes = C6H2Me3-2,4,6) (Lidmpt) affords the monomeric molybdenum trithiolate Mo(η7-dmpt)(η1-dmpt)2, 1, which is spectroscopically and structurally characterized; the MoS3 array has distorted trigonal pyramidal geometry which is caused by strong π-interactions between molybdenum and an ortho-mesityl group from one of the thiolate substituents.

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Article information

DOI
https://doi.org/10.1039/A803064B
Article type
Paper

Chem. Commun., 1998, 1689-1690

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Synthesis and characterization of the monomeric molybdenum trithiolate Mo(η7-dmpt)(η1-dmpt)2 (dmpt = 2,6-dimesitylphenylthiolate)

B. S. Buyuktas and P. P. Power, Chem. Commun., 1998, 1689 DOI: 10.1039/A803064B

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