The activation of carbon disulfide by a cluster. The reaction of the µ3-CS complex [{Co(η-C5H5)}2{Fe(CO)2PPh3}(µ3-S)(µ3-CS)] with CS2
Abstract
When [{Co(η-C5H5)}2{Fe(CO)2PPh3}(µ3-S)(µ3-CS)] is refluxed in CS2 solution, it is converted to [{Co(η-C5H5)}2{Fe(CO)PPh3}(µ3-S){µ3-CSC(S)S}] which contains an unusual C2S3 bridging ligand.