Treatment of (E)-alk-1-enyldicyclohexylborane 1 with B-methoxy-9-borabicyclo[3.3.1]nonane (B-MeO-9-BBN) at 0 °C results in transfer of alk-1-enyl group from boron to boron to give B-[(E)-alk-1-enyl]-9-BBN 2 with retention of configuration.
M. Hoshi, K. Shirakawa and A. Arase, Chem. Commun., 1998, 1225 DOI: 10.1039/A801939H
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