The bimetallic rhodium(I) complex [{Rh(nbd)}2(CTV)]- [BF4]2 exists as an infinite self-included chain in the solid state with intracavity CH···π interactions linking the inclusion polymer together; the analogous monometallic complex co-crystallises with the dinuclear species as an inclusion compound with acetone as the guest.
K. S. B. Hancock, Chem. Commun., 1998, 1409 DOI: 10.1039/A801745J
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