An aminothiol axle molecule is so efficient at threading through the macrocycle 24-crown-8 that iodine oxidation produces a [3]-rotaxane in record yield (84%) by literally riveting two rings together.
A. G. Kolchinski, R. A. Roesner, D. H. Busch and N. W. Alcock, Chem. Commun., 1998, 1437 DOI: 10.1039/A800639C
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