X-Ray structure of bridged 2,2′-bi(adamant-2-ylidene) chloronium cation and comparison of its reactivity with a singly-bonded chloroarenium cation
Abstract
The unsymmetrically bridged 2,2′-bi(adamant-2-ylidene) chloronium hexachloroantimonate shows distinctive electrophilic (transfer) chlorination reactivity in comparison with the singly-bonded chloroarenium cation.