Structure and molecular magnetism of the rutile-related compounds M(dca)2, M = CoII, NiII, CuII, dca = dicyanamide, N(CN)2–
Abstract
The isomorphous rutile-related network structures of Co(dca)2, Ni(dca)2 and Cu(dca)2, dca = dicyanamide, N(CN)2–, are shown to behave as ferromagnets (Tc = 9 and 20 K) and a near-paramagnet, respectively.