Hydrogenation of the thiaplatinacycle [Pt{C,S-(CH![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CHC6H4S)}(dppe)] 2 (dppe = Ph2PCH2CH2PPh2) derived from benzothiophene, leads to [Pt{C,S-(CHMeC6H4S)}(dppe)] 3 in which 2H have added and a H-shift has occurred; the X-ray structures of 2 and 3 are reported.
A. Iretskii, H. Adams, P. M. Maitlis, A. Iretskii, J. J. Garcia and G. Picazo, Chem. Commun., 1998, 61 DOI: 10.1039/A706707K
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