Macrocyclic liquid crystals consisting of a biphenyl rigid core and a 2-phenylpyrimidine unit are fused by cyclopalladation giving a novel type of metallomesogens with nematic and smectic mesophases.
B. Neumann, T. Hegmann, C. Tschierske, B. Neumann and R. Wolf, Chem. Commun., 1998, 105 DOI: 10.1039/A706485C
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