Issue 1, 1998

Formation of an unusual tetralithium diplatinum complex [Pt(C[triple bond, length half m-dash]CBut)2(PPh2O)2Li2(µ-H2O)(Me2CO)2]2 containing µ3-PPh2O Ligands

Abstract

The very unusual complex [Pt(C[triple bond, length half m-dash]CBut)2(PPh2O)2Li2(µ-H2O)(Me2CO)2]2 2 is obtained by the reaction of ‘Li2[Pt(C[triple bond, length half m-dash]CBut)4]’ with an excess of PPh2H in acetone–ethanol and possesses an unusual linear chain of four Li atoms sandwiched between two square planar dianionic units trans-OPPh2{Pt(C[triple bond, length half m-dash]CBut)2}PPh2O, to which it is bound through µ3-PPh2O bridging ligands.

Article information

Article type
Paper

Chem. Commun., 1998, 141-142

Formation of an unusual tetralithium diplatinum complex [Pt(C[triple bond, length half m-dash]CBut)2(PPh2O)2Li2(µ-H2O)(Me2CO)2]2 containing µ3-PPh2O Ligands

L. R. Falvello, J. Forniés, A. Martín, L. R. Falvello, E. Lalinde, T. Moreno and J. Sacristán, Chem. Commun., 1998, 141 DOI: 10.1039/A705522F

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