Preparation and structural characterization of naphtho[2,1-d:6,5-d′]bis([1,2,3]dithiazole) NT and π-stacked mixed valence salt [NT]3[BF4]2
Abstract
Naphtho[2,1-d:6,5-d′]bis([1,2,3]dithiazole) NT, prepared by a ‘double Herz’ condensation of 2,6-diaminonaphthalene with S2Cl2, can be electrooxidized to the conductive, π-stacked mixed valence salt [NT]3[BF4]2.