Issue 1, 1998

Zwitterionic alkene polymerization catalyst derived from Cp2Zr(η2-C2H4)PPh2Me and B(C6F5)3

Abstract

The phosphine stabilized ethylene complex of zirconocene, Cp2Zr, reacts with 1 equiv. of B(C6F5)3 to form the girdle-type zwitterion Cp2Zr+(PPh3Me)CH2CH2B(C6F5)3 2, which serves as an ethene polymerization catalyst either with or without added B(C6F5)3.

Article information

Article type
Paper

Chem. Commun., 1998, 127-128

Zwitterionic alkene polymerization catalyst derived from Cp2Zr(η2-C2H4)PPh2Me and B(C6F5)3

Y. Sun, W. E. Piers, Y. Sun and S. J. Rettig, Chem. Commun., 1998, 127 DOI: 10.1039/A705782B

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