Issue 10, 1997

Structure and kinetics of novel cyclophane inclusion compounds

Abstract

A novel cyclophane host compound, 3, featuring a macrocyclic structure with two hydroquinone dimethyl ether and two 1,1-diphenylcyclohexane construction elements assembled via benzylic ether linkages has been synthesised and its inclusion compounds with toluene, 4, and cyclohexanone, 5, have been characterised by thermal analysis and X-ray crystallography. The conformation of the cyclophane is markedly different in the two inclusion compounds. The kinetics of desolvation of 5 are deceleratory and yield an activation energy of 182 kJ mol–1.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1997, 1949-1953

Structure and kinetics of novel cyclophane inclusion compounds

S. Apel, M. Czugler, V. J. Griffith, L. R. Nassimbeni and E. Weber, J. Chem. Soc., Perkin Trans. 2, 1997, 1949 DOI: 10.1039/A702583A

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