Issue 21, 1997
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Desilylation of (Z )-α-dimethylphenylsilyl vinyl sulfides with fluoride ion: 1 revised mechanism for phenyl group migration in substrates containing an electron-withdrawing group β to the sulfur

Bianca Flavia Bonini,   Mauro Comes Franchini,   Mariafrancesca Fochi,   Germana Mazzanti  and  Alfredo Ricci  

Abstract

A detailed investigation of the desilylation of (Z )-α-dimethylphenylsilyl vinyl sulfides with fluoride ion has shown that in substrates containing an electron-withdrawing group β to the sulfur, phenyl group migration occurs as a result of a fluoride ion catalyzed retro-Michael reaction.

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Article information

DOI
https://doi.org/10.1039/A703662K
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1997, 3211-3218

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Desilylation of (Z )-α-dimethylphenylsilyl vinyl sulfides with fluoride ion: 1 revised mechanism for phenyl group migration in substrates containing an electron-withdrawing group β to the sulfur

B. Flavia Bonini, M. Comes Franchini, M. Fochi, G. Mazzanti and A. Ricci, J. Chem. Soc., Perkin Trans. 1, 1997, 3211 DOI: 10.1039/A703662K

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