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Issue 11, 1997
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Conversion of carbonimidodithioates to carbamates

Abstract

Carbonimidodithioates derived from primary amines or α-amino acid esters have been converted to N-benzyloxycarbonyl derivatives under mild conditions by treatment first with sodium benzyl alcoholate and then with water. N-Benzyloxycarbonyl α-amino acids have been generated from the methyl esters by alkaline hydrolysis or from the allyl esters by Pd 0 -catalysed de-allylation.

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Article information


J. Chem. Soc., Perkin Trans. 1, 1997, 1623-1628
Article type
Paper

Conversion of carbonimidodithioates to carbamates

M. Anbazhagan, T. Indrasena Reddy and S. Rajappa, J. Chem. Soc., Perkin Trans. 1, 1997, 1623
DOI: 10.1039/A700166E

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