Issue 12, 1997

Regioselective total synthesis of edulane and its angular analogue

Abstract

Herein we describe a 10-step total synthesis of edulane 3 and its angular analogue 18 from phloroglucinol. The key step involves ZnCl2-catalysed condensation of the appropriately substituted 2H-chromenes 8, 9 and 10 with the 2-alkoxy-1,4-benzoquinones 11 and 12, respectively.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1997, 1875-1878

Regioselective total synthesis of edulane and its angular analogue

K. Subburaj, M. G. Murugesh and G. K. Trivedi, J. Chem. Soc., Perkin Trans. 1, 1997, 1875 DOI: 10.1039/A608227K

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