Issue 3, 1997

Cycloaddition vs. conjugative Michael-type addition of 2-ethoxy-3-morpholinobuta-1,3-diene with nitroolefins

Abstract

The reactivity of the title dienamine towards conjugated nitroolefins has been investigated. With 1-nitrocyclopentene carbocyclic products largely predominated, whereas with 1-nitrocyclohexene only Michael-type products were formed. The behaviour of β-nitrostyrene was found to be dependent on the reaction conditions used.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1997, 223-228

Cycloaddition vs. conjugative Michael-type addition of 2-ethoxy-3-morpholinobuta-1,3-diene with nitroolefins

G. Marc, P. Nitti, G. Pitacco, A. Pizzioli and E. Valentin, J. Chem. Soc., Perkin Trans. 1, 1997, 223 DOI: 10.1039/A605345I

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