Issue 5, 1997

Steric control in the ion radical nitration of 5-triphenylmethylbenzimidazolines using a silver/nitrite system

Abstract

Nitration of 1,2,2,3-tetrasubstituted 5-triphenylmethylbenzimidazolines using an Ag+/NO2- system shows an unexpected (for benzimidazolines) orientation of the nitro group into position 7, which may be due to the strong steric influence of the rather bulky triphenylmethyl substituent.

Article information

Article type
Paper

Mendeleev Commun., 1997,7, 175-176

Steric control in the ion radical nitration of 5-triphenylmethylbenzimidazolines using a silver/nitrite system

A. S. Morkovnik, Mendeleev Commun., 1997, 7, 175 DOI: 10.1070/MC1997v007n05ABEH000817

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